Synthesis and Characterization of Cd Complexes Containing Phenanthroline Derivatives

Niloufar Akbarzadeh-Torbati* and Younes Sarani

Department of Chemistry, University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran.

*Corresponding Author E-mail: n.akbarzadeh@chem.usb.ac.ir

Abstract: Twonew Cd(II) complexes of the type [Cd(opd)(dafone)]NO₃(1) and [cd(phen-dion)(dafone)]NO₃(2)that opd=ortho-phenylenediamine, dafone=4-5 diaza- diazafloren-9-on and phen-dion =1,10-phenanthroline-5,6-dione, have been synthesized.These compounds have been characterized using the IR, UV-Vis, ¹H-NMR spectroscopies and elemental analysis.Also electrochemical behavior of complex (1) and (2) were studied by Cyclic Voltammetric method. The FT-IR results showed that the ligands adduct to metal center as a bidentate ligand by nitrogen atoms.

Keywords: ¹H-NMR spectroscopies; metal center; electrochemical behavior; adduct

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